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ChemInform Abstract: Photoinduced Electron Transfer Oxidation of α-Methylstyrene with Molecular Oxygen Sensitized by Dimethoxybenzenes: A Non-Singlet-Oxygen Mechanism.

✍ Scribed by Tadashi Mori; Makoto Takamoto; Yoshimasa Tate; Junya Shinkuma; Takehiko Wada; Yoshihisa Inoue


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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Photoinduced Electron-Transfer Oxidation
✍ Tadashi Mori; Makoto Takamoto; Takehiko Wada; Yoshihisa Inoue 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 177 KB 👁 2 views

Dedicated to Professor Andre M. Braun on the occasion of his 60th birthday a-Methylstyrene (1) was photo-oxidized in the presence of a series of alkylated dimethoxybenzenes as sensitizers in an oxygen-saturated MeCN solution to afford the cleaved ketone 2, epoxide 3, as well as a small amount of th