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Photoinduced dehydrogenation reaction of CH3NH2 by NO2 in a cryogenic Ar matrix. Identification of the CH2 = NH · H2O complex

✍ Scribed by Nobuaki Tanaka; Junichi Oike; Yoshizumi Kajii; Kazuhiko Shibuya; Munetaka Nakata

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
425 KB
Volume
232
Category
Article
ISSN
0009-2614

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Oxidation of CH3NH2 and (CH3)2NH by NiII
Oxidation of CH3NH2 and (CH3)2NH by NiIII(cyclam)(H2O)23+ in Aqueous Solutions
✍ Dror Shamir; Israel Zilbermann; Eric Maimon; Dan Meyerstein 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB

## Abstract Ni^II^(1,4,8,11‐tetraazacyclotetradecane)^2+^, Ni^II^L^2+^, is a good electrocatalyst for the oxidation of CH~3~NH~2~ and (CH~3~)~2~NH but not of (CH~3~)~3~N. The oxidation kinetics of the amines by Ni^III^L(H~2~O)~2~^3+^ indicate that the amines are good axial ligands to the tervalent