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Photoinduced Charge Separation Promoted by Ring Opening of a Piperazine Radical Cation

โœ Scribed by Lucia, Lucian A.; Whitten, David G.; Schanze, Kirk S.


Book ID
126786303
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
126 KB
Volume
118
Category
Article
ISSN
0002-7863

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Photoinduced ring-opening rearrangement
โœ Kazumi Toriyama; Keichi Nunome; Machio Iwasaki; Tadamasa Shida; Kiminori Ushida ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 217 KB

ESR observation is described of a new type of reaction of alkane radical cations in solid matrices; the cyclobutanc rodi cation in CFCIJ and in SF6 suffers photoinduced ring opening followed by I J-hydride ion transfer to rcarrangc into the but-l-ene radical cation, which further photoisomeiizes int