Photoinduced ring-opening rearrangement
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Kazumi Toriyama; Keichi Nunome; Machio Iwasaki; Tadamasa Shida; Kiminori Ushida
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Article
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1985
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Elsevier Science
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English
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ESR observation is described of a new type of reaction of alkane radical cations in solid matrices; the cyclobutanc rodi cation in CFCIJ and in SF6 suffers photoinduced ring opening followed by I J-hydride ion transfer to rcarrangc into the but-l-ene radical cation, which further photoisomeiizes int