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Photofragment energy distributions and reaction rates of NH from photodissociation of HN3 at 266 nm

โœ Scribed by J.R. McDonald; R.G. Miller; A.P. Baronavski


Book ID
107731528
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
302 KB
Volume
51
Category
Article
ISSN
0009-2614

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Photodissociation of HNCO at 193 nm. NH(
โœ Walter S. Drozdoski; A.P. Baronavski; J.R. McDonald ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 441 KB

An analysis of the primary photodissociation products resulting fro-m the 193 nm photolysis of HSCO is reported\_ The major fngments are NH(a IA, u' = 0) and CO(X '~3. Reaction of NH(a 'A) with 02 and with HIiCO produces only nonemissive products. A rapid E-E, V energy transfer occurs for collisions

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The angle-velocity distribution of I(2P3/2) and I(2131/2) from photodissociation of (CH3I) n clusters was measured at 266 and 304 nm. For the monomer (n = 1), the angular distribution is very anisotropic and the translational energy spectrum is sharply peaked at high energy. For clusters (predominan