Ab initio SCF MO calculations of the electronic structure of Mn(CO)sH and Mn(CO)sCH 3 predict small (< 0.4 eV) splitting between the metal e and b2 orbitals and lead to a new interpretation of their photoelectron spectra which does not necessitate invoking 7r back-bonding to the -CH 3 group in the c
Photoelectron spectrum and bonding in SiF3Mn(CO)5
โ Scribed by Stephen Cradock; E.A.V. Ebsworth; Alastair Robertson
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 186 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The He I photoelectron spectrzm of pentacarbonyltrifluorosilylmanganese contains a band attributable to the Si-hfn bonding level, at a binding energy of 10.4 eV. The corresponding band for the Si&-derivative is probabry obscured by the strchger bands neru 9 eV die to the Mn 3d levels.
๐ SIMILAR VOLUMES
The microwave rotational spectrum for the symmetric top, manganese pentacarbonylhydride, was measured in the 5-l 1 GHz range using a pulsed-beam, Fourier transform microwave spectrometer. For HMn(CO), we obtained A=E=907.9841( ) MHz andeqQ(Mn)=-44.22(2)MHz.ForDMn(CO)~,A=B=902.7682(3) MHzandeqQ(Mn)=-
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