𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The microwave spectrum and MnH bond length for HMn(CO)5

✍ Scribed by Stephen G Kukolich; Shane M. Sickafoose

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
360 KB
Volume
215
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The microwave rotational spectrum for the symmetric top, manganese pentacarbonylhydride, was measured in the 5-l 1 GHz range using a pulsed-beam, Fourier transform microwave spectrometer. For HMn(CO), we obtained A=E=907.9841( ) MHz andeqQ(Mn)=-44.22(2)MHz.ForDMn(CO)~,A=B=902.7682(3) MHzandeqQ(Mn)=-45.24(4) MHz.OnlyK=Oand K= 4 transitions were observed, confirming the expected C," symmetry. With other structural parameters constrained to previously reported values, rO ( Mn-H ) = 1.64 ( 4) A. The C,-Mn-C, angle derived from the data is approximately 97 ', if Mn-C-O angles are constrained to 180".

📜 SIMILAR VOLUMES

The bonding and photoelectron spectra of
The bonding and photoelectron spectra of Mn(CO)5H and Mn(CO)5CH3
✍ M.B. Hall; M.F. Guest; I.H. Hillier 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 134 KB

Ab initio SCF MO calculations of the electronic structure of Mn(CO)sH and Mn(CO)sCH 3 predict small (< 0.4 eV) splitting between the metal e and b2 orbitals and lead to a new interpretation of their photoelectron spectra which does not necessitate invoking 7r back-bonding to the -CH 3 group in the c

Singlet–triplet splitting and the activa
Singlet–triplet splitting and the activation of CH bond for (η5-C5H5)M(CO) isoelectronic fragments: A theoretical study
✍ Ming-Der Su; San-Yan Chu 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 472 KB 👁 1 views

st oxidative addition reactions to alkane C-H bonds. In contrast, a lighter transition-metal Ž . center i.e., the second row will result in a larger ⌬ E and then tend to undergo the st reductive elimination reactions of the C-H bond-forming. The results obtained are in good agreement with the availa