Photoelectron spectroscopy of liquids: relationships between ionization energy and reduction potential
β Scribed by R.E. Ballard
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 175 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The s;andard (reduction) potential of a half-cell, E, and the phctoelectric work function, W(eV), are related by W = E f 4.4. EmpirIcal relationships between the gas-phase ionkatlon energy and polarographtc half-wave potentials are given a theoretical basis.
π SIMILAR VOLUMES
A relationship between the energy of the highest occupied molecular orbital (HOMO) and the oxidation potential of molecular organic semiconductors is presented. Approximating molecules as dipoles consisting of a positively charged ion core surrounded by an electron cloud, the HOMO energy (E HOMO) is
TIC rlecwonic spectra and ektrochemical pokntials of the speck [Ru(bipy).(NN),\_ r]2' (bipy = 2.2'-bipyridme. NN = unsamrared dlimine. x =l.?) arc corrclnkd via rundamenlnl relalionships involving rrorganisnrion and salvation energ~~ It is argued char the presence of two distinct RP -hgand charge ln