Photoelectron spectroscopy of carbonyls. Ionization assignments
โ Scribed by J.L. Meeks; J.F. Arnett; D. Larson; S.P. McGlynn
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 549 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
mnizatlon b.md of ethyl radical bns been okcrvcd HI 3 photoelectron spectrometer. i'hc adlabdtic and ~rtic,d P's are 8.30 t: 0.02 eV and 8.55 + 0.02 cV, respcctivcly, and tbc beat ot formatIon of CzltIf is calculated to be 217.1 + "r-1 bcal/mol. Our data arc m good agreement with prcv~ou~ results.
The s;andard (reduction) potential of a half-cell, E, and the phctoelectric work function, W(eV), are related by W = E f 4.4. EmpirIcal relationships between the gas-phase ionkatlon energy and polarographtc half-wave potentials are given a theoretical basis.