Photoelectron spectra of cyclopentanone and cyclohexanone enamines.

✍ Scribed by N. Domelsmith; K.N. Houk

• Book ID: 104235955
• Publisher: Elsevier Science
• Year: 1977
• Tongue: French
• Weight: 187 KB
• Volume: 18
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)83658-3

✦ Synopsis

In the course of a study of the relationships between the electronic structures of anamines and the rates of reactions of these species, we have encountered some differences between IP's reported in the literature and those found in our laboratories. In order to show in a preliminary way how alkene ring-size and the nature of the amine affect enamine IP's, and to give photoelectron spectral evidence for the pyramidal nature of the enamine nitrogen, we report here the photoelectron spectra of the pyrrolidine, piperidine, and morpholine enamines of cyclopentanone and cyclohexanone.