𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photodissociation spectroscopy of Mg+—Ar

✍ Scribed by J.S. Pilgrim; C.S. Yeh; M.A. Duncan

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
481 KB
Volume
210
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Mg+-Ar ion-molecule complexes are produced in a pulsed supersonic nozzle cluster source. The complexes are mass selected and studied with laser photodissociation spectroscopy in a reflectron time-of-flight mass spectrometer system. An electronic transition assigned as X 2Z++211 is observed with an origin at 31387 cm-' (vat) for 24Mg+-Ar. The 24Mg+-Ar spectrum is characterized by a 15 member progression with a frequency (0:) of 272 cm-'. An extrapolation of this progression fixes the excited state dissociation energy (Db) at 5552 cm-'. The corresponding ground-state value ( 06) is 1270 cm-' (3.6 kcal/mol). The 211,,,,s,2 spin-orbit splitting is 76 cm-'.

📜 SIMILAR VOLUMES

Photodissociation spectroscopy of Mg+H2
Photodissociation spectroscopy of Mg+H2O
✍ C.S. Yeh; K.F. Willey; D.L. Robbins; J.S. Pilgrim; M.A. Duncan 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 398 KB

Mg+-H20 ion-molecule complexes are produced in a pulsed supersonic nozzle cluster source. These weakly bound complexes are mass selected and studied with laser photodissociation spectroscopy in a reflectron time-of-flight mass spectrometer system. An electronic transition assigned as 2B2--}X 2A1 is

Photodissociation of Ar+3 cluster ion
Photodissociation of Ar+3 cluster ion
✍ Takashi Nagata; Jun Hirokawa; Tsutomu Ikegami; Tamotsu Kondow; Suehiro Iwata 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 561 KB

The time-of-flight spectra of Ar+ produced in the photodissociation of Ar: were observed in the wavelength range of 460-590 nm. Analysis revealed that (I ) the kinetic energy distribution of Ar\* fragments is bimodal: the components having a released kinetic energy of x0.5-1.0 eV (fast component) an

Photodissociation of Ar+n cluster ions
Photodissociation of Ar+n cluster ions
✍ Takashi Nagata; Jun Hirokawa; Tamotsu Kondow 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 472 KB

The pholofragment time-of-flight (TOF) spectra of Arz (4~n66) were measured in the wavelength range of 465-585 nm. The photofragment observed were Ar+ and A$. Analysis of the TOF spectra revealed that the angular and the kinetic energy distributions of the Ar\* fragment resemble those observed in t

Trapped ion photodissociation spectrosco
Trapped ion photodissociation spectroscopy. Photodissociation of p-dichlorobenzene cation
✍ Toshiki Sasaki; Naohiko Mikami 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 346 KB

Photodissociation of pC6H,C1a cation stored in a rf ion trap cell was investigated by observing fragment yield spectra in the 312-327 nm region. The CsH: generation was found to be induced by the two-photon excitation enhanced with the resonance on the &-% transition of the parent cation. On the oth

Translational spectroscopy of HNCO photo
Translational spectroscopy of HNCO photodissociation
✍ Thomas A. Spiglanin; David W. Chandler 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 479 KB

The kinetic energy released in the photodissociation of HNCO is measured by photofragment translational spectroscopy. In this study, CO is ionized by laser ionization immediately following its ejection from HNCO. The time for the CO ions to travel the length of our spectrometer is then measured, and