The production of Cl atoms in the laser flash photolysis of ClOOCl at 308 nm has been investigated by time-resolved atomic resonance fluorescence at 235 K. A value of @= 1.03 f 0. I2 has been obtained for the primary quantum yield based on an absorption cross section ratio u&u~~s=22 for CIOOCI at 24
Photodissociation quantum yield of NO2 in the region 375 to 420 nm
β Scribed by A.B. Harker; W. Ho; J.J. Ratto
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 318 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The absolute absorption cross section and photodissociation quantum yield of NO;! were determined over the wavelength region 375 to 420 nm at a temperature of 296 K. The quantum yield measurements were made at 1 nm intervals over this frequency range with an accuracy of + 7%. The data show a significant decrease in the quantum yield between 380 and 390 nm indicating thr possibility of a non-dissociating NO2 excited state in this region.
π SIMILAR VOLUMES
We report the first observation of the Liz diffuse band in the region of 420 nm which is the analog of the diffuse bands in other alkali diier spectra, for example. at 436.5 and 575 nm for the sodium and potassium cases, respectively\_ The observed diffuse band appears to arise from the 2 311g-l 'Xi
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Rotational population distributions of NO photofragments in the second vibrational excited state from the photofragmentation of NO2 at 337 nm are evaluated numerically via a kinematic distribution function. The kinematic constraints on the final state interaction in the photofragmentation process of