The objective of this Letter is to emphasise the importance of using the correct angular momentum selection rules and angular momentum coupling algebra when computing fragment rotational quantum state distributions in molecular photodissociation processes. Because the effort required for the computa
PHOTODISSOCIATION OF OZONE IN THE HARTLEY BAND: FRAGMENT ROTATIONAL QUANTUM STATE DISTRIBUTIONS
β Scribed by ZHAO, MEI-YU; HAN, KE-LI; HE, GUO-ZHONG; ZHANG, JOHN Z. H.
- Book ID
- 120641371
- Publisher
- World Scientific Publishing Company
- Year
- 2004
- Tongue
- English
- Weight
- 217 KB
- Volume
- 03
- Category
- Article
- ISSN
- 0219-6336
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The coherent anti-Stokes Rarnan scattering (CARS) spectrum of O#A~) formed in the photodissociation of ozone at 266 MI is presented. An anomalous propensity for even (J= 2,4,6, \_..) rotatronal states is observed. This propensity effect is discussed in terms of symmetry restrictions and dynamical bi
## Abstract The absolute quantum yield of O(^1^__D__~2~) in the photolysis of ozone in the Hartley band, between about 230 and 280 nm, has been determined using the isotopic exchange reaction between C^16^O~2~ and ^18^O(^1^__D__~2~). A value of 1.00 Β± 0.05 has been obtained within a 95% confidence
The kinematic constraints on the final-state interaction in photodissociation processes of triatomic molecules are studied. Numerical evaluations of the rotational population distributions of HS photofragments have been implemented. Good agreement between the calculated distributions and experimenta