The kinematic constraints on the final-state interaction in photodissociation processes of triatomic molecules are studied. Numerical evaluations of the rotational population distributions of HS photofragments have been implemented. Good agreement between the calculated distributions and experimenta
Anomalous rotational state distribution for the O2 photofragment in the UV photodissociation of ozone
โ Scribed by James J. Valentini
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 327 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The coherent anti-Stokes Rarnan scattering (CARS) spectrum of O#A~) formed in the photodissociation of ozone at 266 MI is presented. An anomalous propensity for even (J= 2,4,6, _..) rotatronal states is observed. This propensity effect is discussed in terms of symmetry restrictions and dynamical bias in the photolysis.
๐ SIMILAR VOLUMES
We employ a semi-empirical model that utilizes a kinematic distribution function to calculate the rotational state population distributions of diatomic photofragments from the photodissociation of isotopically variant triatomic molecules. The numerically evaluated rotational distributions of tbe pho