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Photodissociation of ozone at 193 nm by high-resolution photofragment translational spectroscopy

โœ Scribed by Stranges, Domenico; Yang, Xueming; Chesko, James D.; Suits, Arthur G.


Book ID
121745838
Publisher
American Institute of Physics
Year
1995
Tongue
English
Weight
407 KB
Volume
102
Category
Article
ISSN
0021-9606

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The photodissociation of the halon CF&Cl has been studied by the time-of-flight crossed-laser molecular-beam method at 193 nm. Two primary decays are operative, the dominant one yielding CFsCl+Br (DA') = 63.5 f 3 kcaJ/mol) with Br( 'P1,s): Br(\*P,,,) ~2: I and the second one CF,Br+CI (06s) =78 &4 kc

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We have generated a cold beam of the highly corrosive sulfur trioxide SO3 and have studied its photodissociation at 193 nm by photofragment translational spectroscopy, The spin-allowed process SO3( g 'A{) + hv --+ SOs( ji 'Al ) + 0( 'D) was found to be the primary dissociation channel. A part of the