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Photodissociation of homonuclear diatomics: Fine structure cross sections for Na2(X1Σg+) → Na(2S1/2) + Na(2P1/2,3/2

✍ Scribed by Walter S. Struve; Sherwin J. Singer; Karl F. Freed

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
498 KB
Volume
110
Category
Article
ISSN
0009-2614

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✦ Synopsis

Exact quantum calculations are presented for fine structure cross sections in photodissociation of Naz. Resonance peaks in the NzI(~P,,) cross section arise from the highest two quasibound levels supported by the electronic barrier in the B *$ state. Long-range non-adiabaticity is rendered negligible by large resonant dipole splittings between electronic states.

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