✦ LIBER ✦

Electronic angular momentum effects on photodissociation: fine structure cross sections and angular distributions for NaH → Na(2P12,32) + H(2S12)

✍ Scribed by Sherwin J. Singer; Karl F. Freed; Yehuda B. Band

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 443 KB
Volume: 91
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)87022-x

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✦ Synopsis

Quantum-mechamal

calculatmns are presented for the NaH -c Na(zPln,sn) + H(%,& photodlssoclauon process. Non-adlabatc couplmgs are present when fragments possess non-vamshmg eIectromc angular momentum and are essentnil to descIlbe the low-energy cross sectlons and angular dlstrlbutlons. Cor~ob and spm-orblt mteractions conxderably affect the Na2P3n.*P1,2 branchmg ratio and angular dlstrtbutlons Lowenergy resonance phenomena a .: found, mcludiig ones arlsing from non-adlahatlc spm-orblt couplmg.