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Photodissociation of aromatic azides

โœ Scribed by Budyka, M F


Book ID
125456301
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
253 KB
Volume
77
Category
Article
ISSN
0036-021X

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Photolytic decomposition of phenyl azide in ethanethiol gives o-thioethoxyaniline (1) in 39% yield. This is an unexpected result as phenyl azide usually undergoes ring expansion to 2-substituted 3H-azepines when decomposed in nucleophilic solvents, such as primaryl, secondary', and tertiary2 3 aliph