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Effect of diphenylamine on photodissociation of aryl azides

โœ Scribed by M. F. Budyka; M. M. Kantor; R. M. Fatkulbayanov

Publisher
Springer
Year
1997
Tongue
English
Weight
316 KB
Volume
46
Category
Article
ISSN
1573-9171

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## Photocyclization of diphenylamine (DPA) in cyclohexane is accelerated by the addition of hydrogen-bonding agents (Q). Laser photolysis studies reveal that Q principally affects the S1 state of DPA. DPA in its S1 state forms a stable hydrogen-bonding complex with Q in which DPA acts as a proton