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Photodissociation dynamics of the D2H+ molecular ion

✍ Scribed by M. Berblinger; J.M. Gomez-Llorente; E. Pollak; Ch. Schlier

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 401 KB
Volume: 146
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87458-x

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✦ Synopsis

Using a sudden transition state theory we find that photodissociation of long-lived resonances of DzH+ leads to the H+ fragment for total angular momentum JC 27 while D+ is formed for J> 30. This quantum result which is critically dependent on the difference of zero-point energies between D2 and HD explains an additional aspect of the Carrington-Kennedy experiments.

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