Photodimerization of prenyl mercaptan
โ Scribed by Kunihiko Takabe; Takao Katagiri; Juntaro Tanaka
- Book ID
- 104222542
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 99 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Allylic meroaptans have been known to be relatively unstable compound8 and to be polymerized to the polysulfide thiols 1),2)* Moreover, Obata and Tanaka reported that prenyl mercaptan(Y,Y-dimethyl ally1 mercaptan)(I) was the major
๐ SIMILAR VOLUMES
It haa been Imown that prenyl halides (3-methyl-2-butenyl halide81 ') and prenyl acetate 2) were dimeriaed to the lavandulyl compounde, the 4,3-coupling monoterpenee, eeleotively by the a&ion of the acid& In the oaae of prenyl thiol aoetate (I), S-lavandulyl compound6 could be obtained hardly and th
In 1949 Coyneg)and Bayer 'reported tha t thermal dimarization of acrylonitrile produced 1,2-dicyanocyclobutane. We have found that acrylonitrila dimerises into 1,2-dicyanocyclobutane photochemically in the presence of sensitisersf). In a typical example, a solution