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The addition of the prenyl cation to prenyl thiol acetate

✍ Scribed by Kunihiko Takabe; Takao Katagiri; Juntaro Tanaka

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
188 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

It haa been Imown that prenyl halides (3-methyl-2-butenyl halide81 ') and prenyl acetate 2) were dimeriaed to the lavandulyl compounde, the 4,3-coupling monoterpenee, eeleotively by the a&ion of the acid& In the oaae of prenyl thiol aoetate (I), S-lavandulyl compound6 could be obtained hardly and the sulfide thiol acetate (II) was a main product (cf. Table

2) (Beaction A).

The reaction of prenyl aoetate with (I) by aluminium chlo-5o"c),

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