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Photodimerisation of 1,4-cyclohexadiene-1,2-dicarboxylic anhydride

✍ Scribed by Göran Ahlgren; Björn Åkermark


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
109 KB
Volume
15
Category
Article
ISSN
0040-4039

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1,4-dicarbonyl-2,5-cyclohexadiene
✍ Marquardt, Ralph ;Sander, Wolfram ;Laue, Thomas ;Hopf, Henning 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 455 KB

## Abstract The mechanism of the photolysis of [2.2]paracyclophane‐1,10‐dione (9) was investigated in solution and in argon matrices. The first step of the photolysis involves α‐cleavage of the cyclophane yielding a diradical 11 which could be trapped by ethanol. In argon at 10 K the diradical rapi