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Photodihydrodimerization of some cyclopropyl conjugated 1,2-diketones

✍ Scribed by J. Kelder; H. Cerfontain

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 212 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84613-x

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✦ Synopsis

We have studied the behaviour of three cyclopropyl conjugated 1,2-diketones (I a, b, and c) ' in isopropanol upon irradiation with a Philips SP 500 W mercury lamp (with 436 nm as the most intense line). For comparison we extended this study to three non-cyclopropyl containing 1,2-diketones, viz. biacetyl (Id), 1-phenyl-1,2-propanedione (I e) and benzil (I f).

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