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Photodegradation of poly(methyl methacrylate) studied by ESR and viscosity measurements

✍ Scribed by Ayako Torikai; Kenji Fueki


Book ID
116092446
Publisher
Elsevier Science
Year
1982
Weight
465 KB
Volume
2
Category
Article
ISSN
0144-2880

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It has been found that methyl salicylate (MS) undergoes a photoinduced decarboxylation to form phenol with a quantum yield of ca. 8 x The reaction is first order and the rate constant is proportional to the irradiance used. An activation energy of 1.2 kcal/mol was determined. Computer simulations w