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Photocycloadditions of some alkyl ketones to 1,2-dicyanoethylene maleic anhydride and 1-methoxy-1-butene

✍ Scribed by Turro, Nicholas J.; Wriede, Peter A.


Book ID
126210616
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
577 KB
Volume
34
Category
Article
ISSN
0022-3263

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Most workers assume that the simple ene reaction' involves a concerted mechanism with the same syn-syn stereochemistry as the familiar Diels-Alder reaction. Actually, however, only those stepwise reactions involving initial hydrogen or proton transfer from the ene to the enophile are rigorously elim