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Photocycloaddition of 2-Oxopyran-3-carbonitriles to 2,3-Dimethylbut-2-ene

✍ Scribed by Dirk Schwebel; Jeanette Ziegenbalg; Jürgen Kopf; Paul Margaretha


Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
98 KB
Volume
82
Category
Article
ISSN
0018-019X

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Photoaddition of Ethyl 2,2-Dimethyl-5-ox
✍ Christophe Jeandon; Ralf Constien; Volker Sinnwell; Paul Margaretha 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 248 KB 👁 1 views

## Abstract On irradiation (350 nm) in the presence of excess 2,3‐dimethylbut‐2‐ene, the newly synthesized title compound 5 affords as main products the unexpected cyclopropylpyrrolidine 10 (50%) and the spiro‐oxetane 9 (25%).