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Photocyclizations of 5-acylbicyclo[2.2.2]octenes

✍ Scribed by Sauers, Ronald R.; Whittle, J. A.


Book ID
126942051
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
497 KB
Volume
34
Category
Article
ISSN
0022-3263

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Synthesis and chemistry of sesquibicyclo
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Cationic rearrangements of functionalized spiro (norbornane-7,3'-bicyclo[2.2.2]octan-2'-ols) provide synthetic access to two novel polycarbocyclic alkenes, i.e., 5 and 10 ("sesquibicyclo[2.2.2]octene"). X-ray crystallographic analysis of 5 and 10 reveals that each alkene C=C double bond is planar in