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Intramolecular [2 + 2] photocyclizations. 2. Total synthesis of (.+-.)-hibiscone C (gmelofuran)

โœ Scribed by Koft, Emil R.; Smith, Amos B.


Book ID
126297555
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
892 KB
Volume
106
Category
Article
ISSN
0002-7863

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The first asymmetric total synthesis of stoechospermol, a representative spatane diterpene having G, anti, cis-tricycloC5.3.0.02\*6ldecane ring system, was achieved. Using the intramolecular asymmetrifl22+2) photocycloaddition reaction of the diastereomeric ester 11, the readily available butenolide