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An intramolecular [2+2] photocycloaddition-fragmentation approach towards the total synthesis of Asteriscanolide

โœ Scribed by Kevin I. Booker-Milburn; Justin K. Cowell


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
196 KB
Volume
37
Category
Article
ISSN
0040-4039

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Intramolecular [2 + 2] photocycloadditio
โœ Nishimura, Jun ;Ohbayashi, Akihiro ;Ueda, Eiji ;Oku, Akira ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 305 KB ๐Ÿ‘ 1 views

4.n]Metacyclophanes 6 (n = 2 -6), [4.n]paracyclophanes 7 (n = 3 -6), [4~1](4,4')biphenylophanes 8 (n = 3, 4), and C2.3.2.41paracyclophane 9 were obtained from appropriate 1,2-ethano-[2.n]cyclophanes 1 -5 by Birch reduction. Some strained cyclophanes, like la, lb, and 2a, gave linear open-chain compo