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Photochemistry of δ,γ-unsaturated ketones in solution

✍ Scribed by N.C. Yang; Manesse Nussim; D.Robert Coulson

Publisher: Elsevier Science
Year: 1965
Tongue: French
Weight: 179 KB
Volume: 6
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90101-1

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✦ Synopsis

PhotochemicAl addition of carbonyl c-pounds to unsymmetrical olefins yields A mixture of isomeric oxetanes. The major isomer is the one with the oxygen linked to the lesser substituted end of the olefinic bonda Previous investigations on intramolecular oxetane formAtion from the photolysis of &y-unsaturated ketones showed that 2_oxAbicycloC2,2,0lhexAnea (II)

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