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Photochemistry of bicyclic δ-thia-α,β-unsaturated ketones a vinylketene mechanism

✍ Scribed by Tsutomu Miyashi; Nobukazu Suto; Takayuki Yamaki; Toshio Mukai


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
248 KB
Volume
22
Category
Article
ISSN
0040-4039

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A/~tract:. A new, one pot synthesis of bicyclic ethers starting from ct, l~-unsaturated ketones containing an additional isolated olefinic bond is proposed. It relies on highly chemoselective hydrogenation of the enone group to the corresponding alcohol in the presence of supported copper catalysts,