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Photochemistry of [(trifluoromethyl)azo]cyclopropane: a reinvestigation

โœ Scribed by Engel, Paul S.; Wu, Wen Xue

Book ID
126943608
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
379 KB
Volume
55
Category
Article
ISSN
0022-3263

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โœ J. S. Francisco; M. A. Findeis; J. I. Steinfeld ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 572 KB

Bis(trifluoromethy1) peroxide is readily dissociated by multiple infrared photon excitation at COz laser wavelengths. The primary dissociation product is CF30; approximately 85% of the nascent radicals are further dissociated in the laser field to form CFzO and F. The F atoms then react with the rem