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Photochemistry of the cis- and trans-bicyclo[6.1.0]nonan-2-ones

✍ Scribed by Paquette, Leo A.; Eizember, Richard F.


Book ID
127381530
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
771 KB
Volume
91
Category
Article
ISSN
0002-7863

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## Abstract On irradiation (350β€…nm) in the presence of alkenes (2,3‐dimethylbut‐2‐ene, 1,1‐dimethoxyethene, and 2,4,4‐trimethylpent‐1‐ene), benzoxepinone **1** and dioxepinone **2** are converted into mixtures of __cis__‐ and __trans__‐fused oxabicyclo[5.2.0]nonan‐2‐ones. Their relative thermodynam