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cis- and trans-Bicyclo[6.1.0]nonan-2, 3 and 4 ones (1)

✍ Scribed by Kenneth B. Wiberg; Armin deMeijere

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
174 KB
Volume
10
Category
Article
ISSN
0040-4039

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Interconversion of cis- and trans-Fused
Interconversion of cis- and trans-Fused Oxabicyclo[5.2.0]nonan-2-ones
✍ Kerstin Schmidt; Paul Margaretha 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 199 KB

## Abstract On irradiation (350 nm) in the presence of alkenes (2,3‐dimethylbut‐2‐ene, 1,1‐dimethoxyethene, and 2,4,4‐trimethylpent‐1‐ene), benzoxepinone **1** and dioxepinone **2** are converted into mixtures of __cis__‐ and __trans__‐fused oxabicyclo[5.2.0]nonan‐2‐ones. Their relative thermodynam