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Photochemistry of the anthracene chromophore: Synthesis and photochemical isomerization of 1,2-di(9-anthryl)-1-hydroxypropene, a novel simple enol.

✍ Scribed by H.-D. Becker; K. Andersson


Book ID
108382909
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
43 KB
Volume
28
Category
Article
ISSN
0040-4039

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Photochemistry of the anthracene chromop
✍ Hans-Dieter Becker; Kjell Andersson πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 242 KB

Enolization and subsequent methylation of 1,2-di(9-anthryllethanone leads to photolabile E/Z-isomeric a,&substituted dianthrylethylenes. 1,2-Di(9-anthryljpropanone forms a crystalline enol which isomerizes photochemically in solution by a unique H shift. Isolable simple enols typically are stabilize