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Conformation effects in the spectroscopy and photochemistry of 1,2-di(9-anthryl)ethane. A model for the anthracene “excimer”

✍ Scribed by James Ferguson; Masaharu Morita; Miroslav Puza


Book ID
118319158
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
457 KB
Volume
42
Category
Article
ISSN
0009-2614

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Enolization and subsequent methylation of 1,2-di(9-anthryllethanone leads to photolabile E/Z-isomeric a,&substituted dianthrylethylenes. 1,2-Di(9-anthryljpropanone forms a crystalline enol which isomerizes photochemically in solution by a unique H shift. Isolable simple enols typically are stabilize