Photochemistry of SO2 in the vacuum—U.V. II. Luminescence studies
✍ Scribed by C. Lalo; C. Vermeil
- Book ID
- 103489323
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 574 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0047-2670
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The complex, bis(2,2'-bipyridine)-bis-cyanoruthenium(II), (D), forms three detectable ground-state complexes with silver(I): DAg +, D2Ag +, and DAg~ +. The first, DAg ÷, is isolable and strongly luminescent. Both DAg +\* and the oxidized complex, DAg 2+, are stable during photochemical experiments.
## Ion -pair formation from photoexcitation of SO, was studied by negative-ion mass spectrometry using synchrotron radiation in the 15-35 eV photon energy range. Negative ions 0-from SO, were observed. The appearance energy in the photodissociation efficiency curve for 0-is in good agreement with