Photochemistry of cyclic 1,2-diketones: dependence of the photoproducts on the ring size and excited state geometry
✍ Scribed by Hans Cerfontain; PaulL. Verheijdt
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 69 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0047-2670
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📜 SIMILAR VOLUMES
Ihe surface of the lowest excited smgkt state in meth;lne IS analyzed usmg a basis yet composed of 4-3 IC; augmented by a set of one s and three p Rydbergs. The State (IT2 in Td syrnnrctry. 1 Li, In C 2v! is fmnd to bc dissociatlvc to I B I Cllz and ground state &. Vcrtirally a llydbcrg state, 1B1 r
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## Abstract The diastereoselective Bu~4~NCN‐catalyzed addition of TMSCN to cyclic α,β‐epoxyketones has been considered. Good diastereoselectivities were found, depending on the ring size of the starting material. Computational studies account for the observed diastereoselectivities. (© Wiley‐VCH Ve