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Stereochemistry of the Tetrabutylammonium Cyanide Catalyzed Cyanosylilation of Cyclic α,β-Epoxyketones — Dependence of the Diastereoselectivity on the Ring Size.

✍ Scribed by Ana Aljarilla; Ruben Cordoba; Aurelio G. Csaky; Israel Fernandez; Fernando Lopez Ortiz; Joaquin Plumet; Gloria Ruiz Gomez

Publisher
John Wiley and Sons
Year
2006
Weight
20 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Stereochemistry of the Tetrabutylammoniu
Stereochemistry of the Tetrabutylammonium Cyanide-Catalyzed Cyanosylilation of Cyclic α,β-Epoxyketones – Dependence of the Diastereoselectivity on the Ring Size
✍ Ana Aljarilla; Rubén Córdoba; Aurelio G. Csaky; Israel Fernández; Fernando López 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB

## Abstract The diastereoselective Bu~4~NCN‐catalyzed addition of TMSCN to cyclic α,β‐epoxyketones has been considered. Good diastereoselectivities were found, depending on the ring size of the starting material. Computational studies account for the observed diastereoselectivities. (© Wiley‐VCH Ve