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Photochemistry of bicyclo[3.3.1]nonanes having two functional groups at 3,7-positions

✍ Scribed by Takasi Mori; Kwang Her Yang; Kôichi Kimoto; Hitosi Nozaki

Book ID
104249065
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
127 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

Bicyclo(3.3.l)nonane system prefer6 twin chair conformation (1) in which functional groups at 3,7-position6 are extremely close to each other to induce facile tranaannular interaction. Ionic cyclisation of this type of compound8 ie well known to form adamantans derivatives (2.1, but few has been recorded on photochemical reaction6 (3).

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✍ Ma Selma Arias-Pérez; A. Alejo; A. Maroto 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 650 KB

nonan-9-ones, 1-3, l-alkoxycarbonyl derivates, 4, 5 and aand fl3methyl-3-azabicyclo[3.3.1]nonan-9-ols, 6, 7, have been studied by means of the molecular mechanics (MMX) method and ~H, t3C-NMR spectroscopy. Experimental data fit well with theoreticalcalculations. It is found that the conformational b