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Photochemistry of 2,5-dimethyl- and 2,5-di-tert-butyl-1,3,5-hexatrienes: conformation and reactivity — a quantitative study

✍ Scribed by A.M. Brouwer; J. Cornelisse; H.J.C. Jacobs

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
768 KB
Volume
42
Category
Article
ISSN
1010-6030

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Steric perturbation of the conjugated tr
Steric perturbation of the conjugated triene chromophore. Conformational analysis of (E)- and (Z)-3-methyl-1,3,5-hexatriene and (Z)-3-tert-butyl-1,3,5-hexatriene
✍ A. M. Brouwer; L. Bezemer; H. J. C. Jacobs 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 614 KB

## Abstract A theoretical and NMR‐spectroscopic conformational analysis is presented of the 3‐methyl‐1,3,5‐hexatrienes and of (__Z__)‐3‐__tert__‐butyl‐1,3,5‐hexatriene. It is shown that (__E__)‐3‐methyl‐1,3,5‐hexatriene exists mainly as the __tEt__ rotamer and (__Z__)‐3‐methyl‐1,3,5‐hexatriene as t