Photochemistry of 2,5-dimethyl-1,3,5-hexatrienes in argon matrices. Formation of isomers and rotamers
β Scribed by A. M. Brouwer; H. J. C. Jacobs
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 908 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0165-0513
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## Abstract The photochemistry of the Ξ±βdiazo sulfoxide **7** has been investigated in solid argon at 10 K by IR spectroscopy. The sulfinyl carbene was not detected directly but instead underwent photochemically induced heteroβWolff rearrangement to the sulfine **8** which could be detected and cha
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