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Photochemistry of 2,4-Cyclohexadienones

✍ Scribed by Gerhard Quinkert


Book ID
104613044
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
170 KB
Volume
28
Category
Article
ISSN
0044-2402

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Photochemistry of 4,4-Dialkoxy-2,5-cyclo
✍ Paul Margaretha πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 250 KB

## Abstract Irradiation (Ξ» > 370 nm) of 4,4‐dimethoxy‐2,5‐cyclohexadienone (**1 a**) in benzene affords mainly the ketene acetal **4 a**, which then undergoes further rearrangement. The carbomethoxycyclopentenones **6** and **7** were isolated in modest yields (10–15Β°). It is conceivable that the l