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Photochemistry of 1-Methoxybicyclo[2.2.2] octenones; Photolytic Cyclopropane Cleavage of the Initially Formed Tricyclo [3.3.0.02,8]octan-3-ones

✍ Scribed by Dr. Martin Demuth; Dr. Bernhard Wietfeld; Dr. Bipin Pandey; Prof. Dr. Kurt Schaffner


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
221 KB
Volume
24
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


Photochemie von 1-Methoxybicyclo[2.2.2]o
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Die I-Methoxybicyclo[2.2.2]octenone la-c liefern in einer triplettsensibilisierten Photoreaktion die Bicyclo[3.3.0]octandione 3a-c (Schema 1 ; fur l a -+ 3 a siehe ['I). Diquinane wie 3 sind wertvolle Synthe~ebausteine~~." und mit modifizierten Derivativen konnten Naturstoffe wie Pentalenolacton syn

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## Synthesis of the Pseudoguaianolide and Guaianolide Skeleton by Cleavage of the Ether Bridge of 8-Oxabicyclo[3.2.1]octan-3-one Derivatives. -The ZrCl 4 -promoted cleavage of the ether bridge of title oxabicyclooctane (I) provides, depending on the reaction conditions used, various types of poly