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Photochemie von Benzisoxazolen. (vorläufige Mitteilung)

✍ Scribed by W. Heinzelmann; M. Märky


Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
378 KB
Volume
57
Category
Article
ISSN
0018-019X

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**Synthesis of (±)‐α‐Chamigrene** __Cis__‐ and __trans__‐β‐ionol (__cis__ and __trans__‐**1**) underwent acid catalysed dehydration to a mixture of the tetraenes **2–5** in 70–80% yield (Table 1). Irradiation of this mixtures made the 6‐(__Z__), 8‐(__Z__)‐isomer **5** accessible (columns 3 and 4 in