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Kristallisiertes Betanin. Vorläufige Mitteilung

✍ Scribed by H. Wyler; A. S. Dreiding


Publisher
John Wiley and Sons
Year
1957
Tongue
German
Weight
124 KB
Volume
40
Category
Article
ISSN
0018-019X

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## Abstract An empirical formula (C~24~H~28–30~O~13~N~2~) and certain structural features of betanin are reported. In the beet betanin is accompanied by three related violet compounds.

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## Abstract By degrading betanidin with alkali under exclusion of oxygen it was possible to demonstrate the formation of 4‐methylpyridine‐2, 6‐dicarboxylic acid (II), 2, 3‐dihydro‐5, 6‐dihydroxyindole‐2‐carboxylic acid (IV) and formic acid. Compounds II and IV were also found after a treatment with

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## Abstract __Betanin__, the violet‐red pigment of the beet, and its aglucone, __betanidin__, were converted by mild methods to several derivatives of a new structure, called __neobetanidin__. On the basis of elementary analyses, transformations, color changes with acid, mass‐spectrographic evidenc

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## Abstract A choice between structures I and III for betanidin is now possible in favour of I on the basis of the formation of a well‐characterized di‐O‐acetylderivative (II). The instability of betanidin and its ready transformation into other products at elevated pH's are shown to be due to its