Photochemically initiated polymerization of ε-caprolactone
✍ Scribed by R.I. Dryagileva; T.S. Ivanova
- Book ID
- 116049273
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 295 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0032-3950
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The mechanism of initiation of e-caprolactone polymerization by stable salts has been investigated. Gel permeation chromatography and ~H-NMR spectroscopy were used for determining the compositions of the reaction mixtures and of the polymers. It was established that the initiation proceeds by additi
Polymerization of 1-caprolactone had been investigated with cyclopentadienyl sodium as an initiator. The effects of reaction time, temperature, and concentration of the initiator on the yield and molecular weight of the polymer were discussed. It was shown that the high molecular weight of poly(1-ca
## Abstract The influence of the reaction conditions (time, temperature, concentrations of the monomer, and the initiator) on the amount and composition of the oligomers and high molecular products formed during the heterogeneous anionic polymerization of ϵ‐caprolactone was investigated. The polyme
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