Photochemically induced olefin oxidation by titanyl and vanadyl porphyrins
β Scribed by E.M.K. Mansour; P. Maillard; P. Krausz; S. Gaspard; C. Giannotti
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 321 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0304-5102
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Several remarkable selectivities in competitive epoxidations using a ruthenium porphyrin / 2,6-disubstituted pyridine N-oxide system were observed. The pro fp sal that the active intermediate of this system differed from the trarrsdioxo complex of ruthenium porp yrin was indicated. Much research ha
## Abstract To determine whether peroxynitrite at the concentration and duration present after spinal cord injury induces protein oxidation and nitration in vivo, the peroxynitrite donor 3βmorpholinosydnonimine (SINβ1) was administered into the gray matter of the rat spinal cord for 5 hr. The cords