Photochemical Studies. XLVIII. The Reactions of Methyl Radicals with Oxygen 1
β Scribed by Martin, R. Bruce; Noyes, W. Albert
- Book ID
- 126121146
- Publisher
- American Chemical Society
- Year
- 1953
- Tongue
- English
- Weight
- 409 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The reaction of hydrogen atoms with diazomethane was used as a source of methyl radicals to study the reaction of oxygen atoms with methyl radicals. This investigation verifies directly the earlier results that formaldehyde is a major product and that the rate constant is greater than 3
## Abstract The reaction of methyl radicals with atomic and molecular oxygen was studied with a photoionization mass spectrometer. The methyl radicals were generated by reacting oxygen atoms with ethylene in a fastβflow tube reactor. The rate constant for the reaction of methyl radicals with oxygen