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Photochemical reduction of n-tosylsulfilimines with thiolate anion

โœ Scribed by K. Fujimori; H. Togo; Y. Pelchers; T. Nagata; N. Furukawa; S. Oae

Book ID
104222326
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
230 KB
Volume
26
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The neation between N-toby~diahy.&u&l%i.n~ and p-to.LummthioLafe anion did not .tatahe place i.n the dahh even upon heating up to 62' bti ptoceeded bk?IOOd'Lk?q upon Wan with v.i.&&& figti A UMF at boom temp~uA&, a~~ohd.&g S-N bond c&.avage ptlociuti.

We reported earlier that the following SN2 reaction took place when an optically active alkyl N-tosylsulfilimine was treated with thiolate anion (Eq.l),') whereas the reaction between N-tosylsulfilimines and p-toluenethiolate anion was deemed to result in the reductive S-N bond cleavage of the sulfilimine (Eq.2). 1) In order to examine the possibility that the n-C6H15 Ph.

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